Multi-elemental and Strontium-Neodymium Isotopic Signatures in Charred Wood: Potential for Wood Provenance Studies
نویسندگان
چکیده
Abstract The chemical composition of the wood reflects soil over which corresponding tree has developed. Multi-elemental and isotopic signatures, are characteristic underlying rock substrates, potentially powerful tools for determining provenance. These tracers special interest charred archaeological because they circumvent some limitations dendrochronological provenancing linked to tree-ring loss. However, thermal degradation may introduce a significant bias in analyses. This experimental study focused on effects carbonization temperature three geochemical markers: elemental signatures strontium neodymium ( 86 Sr/ 87 Sr 143 Nd/ 144 Nd, respectively). Wood specimens from variety oak trees stand locations were pyrolyzed at four temperatures (ranging 200°C 800°C) analyzed using ICP-MS µ- XRF (X-ray fluorescence) spectroscopy with multiple collection MC-ICP-MS ) (Sr) (Nd) isotope composition. concentration mineral nutrients generally increased temperature, but magnitude enrichment depended element, compartment (sapwood vs. heartwood), geological substrate. concentrations rubidium, strontium, manganese, magnesium, potassium, and, lesser extent, calcium, minimally affected by compartment, ratios between these elements, as well Nd ratios, stable entire range. only selected (calcium or magnesium normalized manganese) successful site discrimination. Therefore, our multi-tracer approach provides promising new information determine provenance wood.
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ژورنال
عنوان ژورنال: International Journal of Wood Culture
سال: 2023
ISSN: ['2772-3194', '2772-3186']
DOI: https://doi.org/10.1163/27723194-bja10019